全文获取类型
收费全文 | 33160篇 |
免费 | 2515篇 |
国内免费 | 1305篇 |
专业分类
电工技术 | 1717篇 |
技术理论 | 2篇 |
综合类 | 1919篇 |
化学工业 | 5526篇 |
金属工艺 | 2007篇 |
机械仪表 | 2258篇 |
建筑科学 | 2599篇 |
矿业工程 | 1068篇 |
能源动力 | 855篇 |
轻工业 | 1941篇 |
水利工程 | 603篇 |
石油天然气 | 2208篇 |
武器工业 | 250篇 |
无线电 | 3649篇 |
一般工业技术 | 3981篇 |
冶金工业 | 1677篇 |
原子能技术 | 414篇 |
自动化技术 | 4306篇 |
出版年
2024年 | 57篇 |
2023年 | 542篇 |
2022年 | 824篇 |
2021年 | 1339篇 |
2020年 | 1106篇 |
2019年 | 826篇 |
2018年 | 1052篇 |
2017年 | 1060篇 |
2016年 | 996篇 |
2015年 | 1295篇 |
2014年 | 1601篇 |
2013年 | 1973篇 |
2012年 | 2124篇 |
2011年 | 2155篇 |
2010年 | 1954篇 |
2009年 | 1955篇 |
2008年 | 1797篇 |
2007年 | 1769篇 |
2006年 | 1896篇 |
2005年 | 1557篇 |
2004年 | 1012篇 |
2003年 | 1004篇 |
2002年 | 848篇 |
2001年 | 695篇 |
2000年 | 731篇 |
1999年 | 862篇 |
1998年 | 725篇 |
1997年 | 642篇 |
1996年 | 575篇 |
1995年 | 482篇 |
1994年 | 373篇 |
1993年 | 269篇 |
1992年 | 213篇 |
1991年 | 162篇 |
1990年 | 121篇 |
1989年 | 102篇 |
1988年 | 85篇 |
1987年 | 53篇 |
1986年 | 52篇 |
1985年 | 25篇 |
1984年 | 20篇 |
1983年 | 15篇 |
1982年 | 16篇 |
1981年 | 10篇 |
1980年 | 8篇 |
1979年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Wenyan Ma Lian-Wei Luo Peihua Dong Peiyun Zheng Xiuhua Huang Chong Zhang Jia-Xing Jiang Yong Cao 《Advanced functional materials》2021,31(45):2105027
Recent studies have demonstrated that dihydrophenazine (Pz) with high redox-reversibility and high theoretical capacity is an attractive building block to construct p-type polymer cathodes for dual-ion batteries. However, most reported Pz-based polymer cathodes to date still suffer from low redox activity, slow kinetics, and short cycling life. Herein, a donor–acceptor (D–A) Pz-based conjugated microporous polymer (TzPz) cathode is constructed by integrating the electron-donating Pz unit and the electron-withdrawing 2,4,6-triphenyl-1,3,5-triazine (Tz) unit into a polymer chain. The D–A type structure enhances the polymer conjugation degree and decreases the band gap of TzPz, facilitating electron transportation along the polymer skeletons. Therefore the TzPz cathode for dual-ion battery shows a high reversible capacity of 192 mAh g−1 at 0.2 A g−1 with excellent rate performance (108 mAh g−1 at 30 A g−1), which is much higher than that of its counterpart polymer BzPz produced from 1,3,5-triphenylbenzene (Bz) and Pz (148 and 44 mAh g−1 at 0.2 and 10 A g−1, respectively). More importantly, the TzPz cathode also shows a long and stable cyclability of more than 10 000 cycles. These results demonstrate that the D–A structural design is an efficient strategy for developing high-performance polymer cathodes for dual-ion batteries. 相似文献
12.
Wen Cao Zhonghua Zhou Chenyu Li Qun Wang Yue Huang Shirley Shen 《Ceramics International》2021,47(2):1807-1818
Sodalime float (SF) glass is widely used in our societies and industries. Hydrothermal corrosion method is one of the effective ways to prepare a superhydrophobic glass, but there is still lack of knowledge about hydrothermal corrosion behavior and mechanism of SF glass. We have hydrothermally treated SF glass at 180 °C for different time, and tried to reveal the aqueous corrosion process of SF glass. We have characterized the morphologies and chemical compositions of samples, and found that (1) the two sides of SF glass have different corrosion resistances, and (2) a multilayer structural coating with a nanoflake layer (Mg-rich gel layer), a nanowire layer (Ca-rich gel layer), and a porous layer (etched layer) is formed on the air-side of SF glass. Based on the experimental results, we have proposed an aqueous corrosion mechanism of SF glass. The insights of the hydrothermal corrosion behaviors and mechanism provide helpful guidelines to glass surface structural control and functionalization. 相似文献
13.
Zhang Baoyin Mo Zeyao Wang Xin Wang Wei Li Gang Zhang Aiqing Cao Xiaolin 《The Journal of supercomputing》2021,77(10):11270-11287
The Journal of Supercomputing - Domain-specific programming frameworks are usually effective to simplify the development of large-scale applications on supercomputers. This paper introduces a... 相似文献
14.
Nagendra Parasad Yadav Ji-Chuan Xiong Wei-Ping Liu Wei-Ze Wang Yun Cao Ashish Kumar Xue-Feng Liu 《电子科技学刊:英文版》2021,19(3):233-242
The quantitative optical measurement of deep sub-wavelength features with sub-nanometer sensitivity addresses the measurement challenge in the semiconductor fabrication process. Optical scatterings from the sidewalls of patterned devices reveal abundant structural and material information. We demonstrated a parametric indirect microscopic imaging (PIMI) technique that enables recovery of the profile of wavelength-scale objects with deep sub-wavelength resolution, based on measuring and filtering the variations of far-field scattering intensities when the illumination was modulated. The finite-difference time-domain (FDTD) numerical simulation was performed, and the experimental results were compared with atomic force microscopic (AFM) images to verify the resolution improvement achieved with PIMI. This work may provide a new approach to exploring the detailed structure and material properties of sidewalls and edges in semiconductor-patterned devices with enhanced contrast and resolution, compared with using the conventional optical microscopy, while retaining its advantage of a wide field of view and relatively low cost. 相似文献
15.
Ping Xiao Jue Wang Lei Fang Zitong Zhao Xiangshi Sun Xiaochen Liu Haiqiang Cao Pengcheng Zhang Dangge Wang Yaping Li 《Advanced functional materials》2021,31(36):2104068
Neoantigen vaccines and adoptive dendritic cell (DC) transfer are major clinical approaches to initiate personalized immunity in cancer patients. However, the immunization efficacy is largely limited by the in vivo trajectory including neoantigens’ access to resident DCs and DCs’ access to lymph nodes (LNs). Herein, an innovative strategy is proposed to improve personalized immunization through neoantigen-loaded nanovaccines synergized with adoptive DC transfer. It is found that it enables selective delivery of neoantigens to resident DCs and macrophages by coating cancer cell membranes onto neoantigen-loaded nanoparticles. In addition, the nanovaccines promote the secretion of chemokine C-C motif ligand 2 (CCL2), CCL3, and C-X-C motif ligand 10 from macrophages, thus potentiating the access of transferred DCs to LNs. This immunization strategy enables coordinated delivery of identified neoantigens and autologous tumor lysate-derived undefined antigens, leading to initiation of antitumor T cell immunity in a personalized manner. It significantly inhibits tumor growth in prophylactic and established mouse tumor models. The findings provide a new vision for potentiating adoptive cell transfer by nanovaccines, which may open the door to a transformative possibility for improving personalized immunization. 相似文献
16.
Jiangkun Cao Aaron Reupert Yicong Ding Lothar Wondraczek 《Journal of the American Ceramic Society》2022,105(4):2616-2624
Tuning the optical properties of active species embedded within a glass matrix by modifying the ligand environment is of interest for luminescence-based technologies, for example, in optical sensing, data transmission, or spectral conversion. Here, we discuss a facile synthesis procedure for a glass-crystal composite material comprising of bismuth (Bi)-doped zirconia within an aluminoborate glass phase. The approach offers tunable and broad photoemission characteristics in the visible spectral region from 400 to 750 nm. Incorporation of Bi ions into the crystal phase enhances the photoemission intensity by two orders of magnitude, with an external quantum efficiency of about 29%. At higher ZrO2 dopant concentration, we observe a red-shift of both the excitation and the emission bands to match commodity ultra-violet light emitting diodes as excitation sources. Encapsulation within the aluminoborate glass phase provides advantageous thermal behavior, with the emission intensity remaining at >80 % of its initial value up to a temperature of 400 K. 相似文献
17.
Huijuan Yang Haifeng Wang Min Huang Guangtian Cao Fei Tao Qing Shen Guanghong Zhou Hongshun Yang 《Comprehensive Reviews in Food Science and Food Safety》2022,21(2):942-963
Mammalian gelatin is extensively utilized in the food industry because of its physicochemical properties. However, its usage is restricted and essentially prohibited for religious people. Fish gelatin is a promising alternative with no religious and social restrictions. The desirable properties of fish gelatin can be significantly improved by various methods, such as the addition of active compounds, enzymes, and natural crosslinking agents (e.g., plant phenolics and genipin), and nonthermal physical treatments (e.g., ionizing radiation and high pressure). The aim of this study was to explore whether the properties of fish gelatin (gel strength, melting or gelling temperature, odor, viscosity, sensory properties, film-forming ability, etc.) could be improved to make it comparable to mammalian gelatin. The structure and properties of gelatins obtained from mammalian and fish sources are summarized. Moreover, the modification methods used to ameliorate the properties of fish gelatin, including rheological (gelling temperature from 13–19°C to 23–25°C), physicochemical (gel strengths from ∼200 to 250 g), and thermal properties (melting points from ∼25 to 30°C), are comprehensively discussed. The relevant literature reviewed and the technological advancements in the industry can propel the development of fish gelatin as a potential alternative to mammalian gelatin, thereby expanding its competitive market share with increasing utility. 相似文献
18.
由于机动目标的逆合成孔径雷达(Inverse Synthetic Aperture Radar,ISAR)成像中存在多普勒扩散现象,易导致成像分辨率降低。针对此问题,在多分量三次相位信号(Cubic Phase Signal,CPS)模型基础上,提出一种基于Radon-CPF-Fourier变换(Radon-Cubic Phase Function-Fourier Transform,RCFT)的机动目标ISAR成像方法。RCFT可实现CPF中自项能量的相干积累,减轻多普勒扩散带来的影响。与现有的基于时频分析和参数估计的ISAR成像算法相比,RCFT的主副比性能提升了至少2 dB,在时频分辨率无损失时具备更好的自项能量积累能力,可获得更高质量的成像结果。仿真验证了所提方法的有效性。 相似文献
19.
Expanded graphite (EG) is introduced into poly(vinylidene fluoride) (PVDF) by melt mixing extrusion with water injection. The results demonstrate that the unfunctionalized EG in composite prepared with water injection exbibits better dispersion than that in the one prepared without water injection due to the promoting role of water during extrusion. Thus, the PVDF/EG composite with loading of 4 wt% prepared by water‐assisted mixing extrusion (WAME) exhibits electrical conductivity of about three orders of magnitude higher than the neat PVDF and one order of magnitude higher than the one prepared without water injection. Comparing to the neat PVDF, the thermal conductivity of the composites prepared with and without water injection is increased by 101.5% and 75.0%, respectively. The introduced EG leads to increased Young’s modulus and tensile strength especially for the composite prepared by WAME. The present work indicates that WAME can promote the dispersion of EG in PVDF matrix without any extra functionalization. 相似文献
20.
针对湖南某钨选厂使用杂醇类起泡剂BK205所产生的泡沫小、性脆、泡沫层薄等不利于二次浮选的特点,采用BK205与新型醚类起泡剂CU组合使用以便实现矿石中钨矿物的高效回收。结果表明,在采用BK205与新型醚类起泡剂CU组合质量比为3∶1、先BK205后CU的加药方式下,小型闭路试验得到精矿WO3品位为30.13%,回收率为78.98%。工业试验表明,组合起泡剂不仅改善浮选泡沫,减少药剂用量,降低药剂成本,而且能获得比原起泡剂更好的工业指标,使钨矿物得到更高效的回收。 相似文献